Email: bbcnoun@gmail.com Whatsapp: 08131667008 CHM305 Question: Under the influence of dilute base or dilute acid, two molecules of an aldelyde may combine to form a ------------------------------------------------. Answer: [C] β-hydroxy aldehyde Question: C = O, -COOH, -COOR and –CN groups are ------------------------------------------------------ and therefore would be expected to deactivate a carbon-carbon double bond toward electrophilic addition. Answer: [C] powerful electron withdrawing groups Question: Hydroxylamine in the form of one of its more stable salts, (hydroxylamine hydrochloride HONH+ 4Cl-) reacts with aldehydes and ketones to form -------------------- Answer: [B] Oximes Question: If a nucleophile add to the β – carbon of α,β – unsaturatedaldehydes or ketones then it is a ------------------------------------------ or a conjugate addition. Answer: [D] 1,4 – nucleophilic addition Question: If a suitable aldehyde is treated with a concentrated aqueous solution of an alkali at room temperature, it yield the appropriate salt of the carboxylic acid and an alcohol, the reaction is called----------- Answer: [C] Cannizaro Reaction Question: The carbonyl group of α,β – unsaturated aldehydes and ketones consists of a nucleophilic oxygen and ----------------------- carbon. Answer: [D] an electrophilic Question: Fehling’s solution is a mixture of equal volume of copper(II)tetraoxosulphate(VI)solution (Fehling solution A) and sodium hydroxide and ---------------------------------------------- (Fehling’s solution B). Answer: [D] potassium sodium tartarate solution Question: α,β – unsaturated aldehydes and ketones also have another ------------------------------- carbon – the β – carbon. Answer: [A] electrophilic Question: The aldehydes are oxidized by Tollen’s reagent in a ------------------------------------------ test Answer: [A] silver mirror Question: When ethyl acetate is treated with sodium ethoxide and the resulting mixture is acidified, it gives ethyl-β- ketobutyrate(ethyl 3-oxobutanoate), generally known as ------------------------------------ Answer: [B] acetoacetic ester